Scientific journal
Название журнала на английском
ISSN 2500-0802
ПИ №ФС77-61154

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ELECTROACTIVE ORGANIC MATERIALS BASED ОN SOLTS OF TIOPIRILIYA AND ELECTROCHEMICAL BEHAVIOR OF THE SOLID PHASE

Dmitrienko T.G. 1 Demidov A.A. 1
1 Saratov state technical university
Experimental dependence of the velocity due to electrochemical reactions at the elecctrodes of the organicion salts number thiopyrilium the magnitude and rate of change of capacity,concentration of the additive in the carbon electrode6,temperature,pressure.Apparent activation energy calculated according to the length of polarization.Found that the highest rate of flow for the electrochemical conversion of the test electrode at a content of cardon black in its composition in an amount of 50 % and such electrode composition can be recommended for further technological development in order to use in solid phase chemical current sources.Shown that the process of electrochemical reduction on the border of the solid electrolyte, the conductive for sodium ions, proceeds according to two – dimensional nucleation. Such an interpretation of the mechanism of the process is consistent with the result of potentiostatic measurements and linear nature of the dependence of the potential and current density at the maximum speed of the potentiodynamic curve of potential sweep.